Ruthenium‐Catalyzed Oxidant‐Free Allylation of Aromatic Ketoximes with Allylic Acetates at Room Temperature
| dc.contributor.author | Manikandan, Rajendran | en_US |
| dc.contributor.author | Madasamy, Padmaja | en_US |
| dc.contributor.author | JEGANMOHAN, MASILAMANI | en_US |
| dc.contributor.department | Dept. of Chemistry | en_US |
| dc.date.accessioned | 2019-03-15T11:24:16Z | |
| dc.date.available | 2019-03-15T11:24:16Z | |
| dc.date.issued | 2015-09 | en_US |
| dc.description.abstract | Substituted aromatic ketoximes reacted efficiently with allylic acetates in the presence of {[RuCl2(p‐cymene)]2} and AgSbF6 in 1,2‐dichloroethane at ambient temperature, providing ortho‐allyl aromatic ketoximes in a highly regioselective manner without an oxidant. In the reaction, the acetate group of allyl acetate acts as a base to activate the CH bond of aromatics. Later, ortho‐allyl aromatic ketoximes were converted into ortho‐allyl aromatic ketones in the presence of HCl. | en_US |
| dc.identifier.citation | Chemistry - A European Journal, 21(40),13934-13938. | en_US |
| dc.identifier.issn | 0947-6539 | en_US |
| dc.identifier.issn | 1521-3765 | en_US |
| dc.identifier.sourcetitle | Chemistry - A European Journal | en_US |
| dc.identifier.uri | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2213 | |
| dc.identifier.uri | https://doi.org/10.1002/chem.201502284 | |
| dc.language.iso | en | en_US |
| dc.publication.originofpublisher | Foreign | en_US |
| dc.publisher | Wiley | en_US |
| dc.subject | Ruthenium‐Catalyzed | en_US |
| dc.subject | Allylation of Aromatic Ketoxime | en_US |
| dc.subject | Allylic Acetates | en_US |
| dc.subject | Room Temperature | en_US |
| dc.subject | Double-bond migration | en_US |
| dc.subject | 2015 | en_US |
| dc.title | Ruthenium‐Catalyzed Oxidant‐Free Allylation of Aromatic Ketoximes with Allylic Acetates at Room Temperature | en_US |
| dc.type | Article | en_US |