Lewis acid-catalyzed stereoselective lactonization and subsequent glycosidation of 2-C-malonyl carbohydrates

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dc.contributor.authorPimpalpalle, Tukaram M.en_US
dc.contributor.authorVIDADALA, SRINIVASA RAOen_US
dc.contributor.authorHOTHA, SRINIVASen_US
dc.contributor.authorLinker, Torstenen_US
dc.contributor.departmentDept. of Chemistryen_US
dc.date.accessioned2019-02-14T05:49:14Z
dc.date.available2019-02-14T05:49:14Z
dc.date.issued2011-08en_US
dc.description.abstractGold(III) bromide is a suitable catalyst for the stereoselective cyclization of 2-C-malonyl carbohydrates to the anomeric center under retention of one ester group. Reopening of the lactones with alcohols in the presence of TMSOTf affords allyl, propargyl and benzyl glycosides with high α-selectivity.en_US
dc.identifier.citationChemical Communications, 47 (37), 10434-10436.en_US
dc.identifier.issn1359-7345en_US
dc.identifier.issn1364-548Xen_US
dc.identifier.sourcetitleChemical Communicationsen_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1763
dc.identifier.urihttps://doi.org/10.1039/C1CC13425F
dc.language.isoenen_US
dc.publication.originofpublisherForeignen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectLewis acid-catalyzeden_US
dc.subject2-C-malonyl carbohydratesen_US
dc.subjectTMSOTf affords allyl, propargylen_US
dc.subjectStereoselective cyclizationen_US
dc.subject2011en_US
dc.titleLewis acid-catalyzed stereoselective lactonization and subsequent glycosidation of 2-C-malonyl carbohydratesen_US
dc.typeArticleen_US

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