An intramolecular phosphine-oxide stabilized germanium(iv) di-cation with enhanced Lewis acidity and catalytic applications

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dc.contributor.authorKUMARI, AKANKSHAen_US
dc.contributor.authorPEDDI, BALAKRISHNAen_US
dc.contributor.authorYildiz, Cem. B.en_US
dc.contributor.authorMAJUMDAR, MOUMITAen_US
dc.contributor.departmentDept. of Chemistryen_US
dc.date.accessioned2025-06-24T11:45:09Z
dc.date.available2025-06-24T11:45:09Z
dc.date.issued2025-05en_US
dc.description.abstractThis work reports the intramolecular phosphine-oxide stabilized tetra-coordinated germanium(IV) di-cation on an acenaphthene platform, 1iPrPO. Computational study shows that the positive charges and the acceptor orbitals are localized on the Ge site. 1iPrPO is Lewis super acidic, capable of catalysing hydrodefluorination reaction. 1iPrPO also catalyses hydrosilylation of electron-deficient aldehydes.en_US
dc.identifier.citationChemical Communications, 61(35), 6506-6509.en_US
dc.identifier.issn1364-548Xen_US
dc.identifier.sourcetitleChemical Communicationsen_US
dc.identifier.urihttps://doi.org/10.1039/D5CC00250H
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/10199
dc.language.isoenen_US
dc.publication.originofpublisherForeignen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectChemistryen_US
dc.subject2025en_US
dc.titleAn intramolecular phosphine-oxide stabilized germanium(iv) di-cation with enhanced Lewis acidity and catalytic applicationsen_US
dc.typeArticleen_US

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