Ruthenium-Catalyzed ortho Alkenylation of Aromatics with Alkenes at Room Temperature with Hydrogen Evolution

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dc.contributor.authorManikandan, Rajendranen_US
dc.contributor.authorMadasamy, Padmajaen_US
dc.contributor.authorJAYAKANNAN, MANICKAMen_US
dc.contributor.departmentDept. of Chemistryen_US
dc.date.accessioned2019-04-29T10:15:50Z
dc.date.available2019-04-29T10:15:50Z
dc.date.issued2016-01en_US
dc.description.abstractA ruthenium-catalyzed oxidant-free highly regioselective ortho alkenylation of substituted aromatics such as aromatic amides, aromatic ketoximes, and anilides with alkenes in the presence of AgSbF6 and acetic acid in ClCH2CH2Cl at room temperature is described. The alkenylation reaction provides ortho alkenylated aromatics along with evolution of H2 gas. In the reaction, no oxidant was used, and the whole catalytic reaction has occurred without changing the oxidation state of the metal.en_US
dc.identifier.citationACS Catalysis, 6 (1), 230-234.en_US
dc.identifier.issn2155-5435en_US
dc.identifier.sourcetitleACS Catalysisen_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2717
dc.identifier.urihttps://doi.org/10.1021/acscatal.5b02218
dc.language.isoenen_US
dc.publication.originofpublisherForeignen_US
dc.publisherAmerican Chemical Societyen_US
dc.subjectRuthenium-Catalyzeden_US
dc.subjectAlkenylationen_US
dc.subjectRoom Temperatureen_US
dc.subjectHydrogen Evolutionen_US
dc.subjectAmbient temperatureen_US
dc.subjectC?H bond activationen_US
dc.subjectHydrogen evolutionen_US
dc.subjectOxidant freeen_US
dc.subjectRuthenium catalysisen_US
dc.subject2016en_US
dc.titleRuthenium-Catalyzed ortho Alkenylation of Aromatics with Alkenes at Room Temperature with Hydrogen Evolutionen_US
dc.typeArticleen_US

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