Total syntheses of (+/-)-taiwaniaquinol D and (+/-)-taiwaniaquinone D via a key Lewis acid-catalyzed Nazarov type cyclization

Kakde, Badrinath N.; Parida, Amarchand; KUMARI, POOJA; Bisai, Alakesh

Total syntheses of (+/-)-taiwaniaquinol D and (+/-)-taiwaniaquinone D via a key Lewis acid-catalyzed Nazarov type cyclization

Date

2016-07

Authors

Publisher

Elsevier B.V.

Abstract

Total syntheses of structurally intriguing taiwaniaquinoids viz (±)-taiwaniaquinol D (1e) and (±)-taiwaniaquinone D (1h) have been disclosed via a key Lewis acid catalyzed Nazarov type cyclization of arylvinylcarbinols.

Keywords

abeo-Abietane, Total synthesis, Nazarov cyclization, Quaternary stereocenter, Taiwaniaquinoids, 2016

Citation

Tetrahedron Letters, 57(29), 3179-3184.

URI

http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/5321
https://doi.org/10.1016/j.tetlet.2016.06.030

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Total syntheses of (+/-)-taiwaniaquinol D and (+/-)-taiwaniaquinone D via a key Lewis acid-catalyzed Nazarov type cyclization

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