A Practical and Convenient Protocol for the Synthesis of (E)-α,β-Unsaturated Acids
| dc.contributor.author | MOHITE, AMAR R. | en_US |
| dc.contributor.author | BHAT, RAMAKRISHNA G. | en_US |
| dc.contributor.department | Dept. of Chemistry | en_US |
| dc.date.accessioned | 2019-02-14T05:00:09Z | |
| dc.date.available | 2019-02-14T05:00:09Z | |
| dc.date.issued | 2013-09 | en_US |
| dc.description.abstract | α,β-Unsaturated acids are very useful and versatile reagents in organic synthesis. A novel, practical, and convenient catalytic protocol comprising FeCl3·6H2O (0.5 mol %) and H2O (1 equiv) in CH3NO2 is described for the rapid synthesis of α,β-unsaturated acids with high E-stereoselectivity under both microwave and conventional heating conditions with high TON and TOF values. This powerful approach efficiently demonstrated the utility of biomass derived aldehydes to build chemical agents used as fuel additives. The method proved to be scalable to gram scale synthesis. | en_US |
| dc.identifier.citation | Organic Letters, 15(17), 4564-4567. | en_US |
| dc.identifier.issn | 1523-7060 | en_US |
| dc.identifier.issn | 1523-7052 | en_US |
| dc.identifier.sourcetitle | Organic Letters | en_US |
| dc.identifier.uri | http://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1584 | |
| dc.identifier.uri | https://doi.org/10.1021/ol402130t | |
| dc.language.iso | en | en_US |
| dc.publication.originofpublisher | Foreign | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.subject | Convenient Protocol | en_US |
| dc.subject | Synthesis of (E)--,-- | en_US |
| dc.subject | Unsaturated Acids | en_US |
| dc.subject | (E)-α,β-Unsaturated Acids | en_US |
| dc.subject | TON and TOF values | en_US |
| dc.subject | 2013 | en_US |
| dc.title | A Practical and Convenient Protocol for the Synthesis of (E)-α,β-Unsaturated Acids | en_US |
| dc.type | Article | en_US |