A Metal Coordination Polymer Framework Governed by Heat of Hydration for Non-invasive Differentiation of Alkali Metal Series

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dc.contributor.authorBattu, Shateeshen_US
dc.contributor.authorItagi, Maheshen_US
dc.contributor.authorBHAT, ZAHID MANZOORen_US
dc.contributor.authorKHAIRE, SIDDHIen_US
dc.contributor.authorKOTTAICHAMY, ALAGAR RAJAen_US
dc.contributor.authorSannegowda, Lokesh Koodluren_US
dc.contributor.authorTHIMMAPPA, RAVIKUMARen_US
dc.contributor.authorTHOTIYL, MUSTHAFA OTTAKAMen_US
dc.contributor.departmentDept. of Chemistryen_US
dc.date.accessioned2018-10-08T03:32:12Z
dc.date.available2018-10-08T03:32:12Z
dc.date.issued2018-10en_US
dc.description.abstractWe illustrate that the extent of hydration and consequently the heat of hydration of alkali metal ions can be utilized to control their insertion/deinsertion chemistry in a redox active metal coordination polymer framework (CPF) electrode. The formal redox potential of CPF electrode for cation intercalation is inversely correlated to hydrated ionic radii, with clear distinction between the intercalation of ions across alkali metal series. This leads to non-invasive identification and differentiation of cations in the alkali metal series by utilizing a single sensing platform.en_US
dc.identifier.citationAnalytical Chemistryen_US
dc.identifier.issn0003-2700en_US
dc.identifier.sourcetitleAnalytical Chemistryen_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1217
dc.identifier.urihttps://doi.org/10.1021/acs.analchem.8b03541
dc.language.isoenen_US
dc.publication.originofpublisherForeignen_US
dc.publisherAmerican Chemical Societyen_US
dc.subject2018en_US
dc.subjectMetal Coordination Polymer Frameworken_US
dc.subjectNon-invasive Di fferentiationen_US
dc.subjectTOC-SEP-2018en_US
dc.titleA Metal Coordination Polymer Framework Governed by Heat of Hydration for Non-invasive Differentiation of Alkali Metal Seriesen_US
dc.typeArticleen_US

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