Enantiopure Polyradical Tetrahedral Pd12L6 Cages

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dc.contributor.authorRAJASEKAR, PRABHAKARANen_US
dc.contributor.authorSwain, Abinashen_US
dc.contributor.authorRajaraman, Gopalanen_US
dc.contributor.authorBOOMISHANKAR, RAMAMOORTHYen_US
dc.contributor.departmentDept. of Chemistryen_US
dc.date.accessioned2021-06-11T04:37:27Z
dc.date.available2021-06-11T04:37:27Z
dc.date.issued2021-07en_US
dc.description.abstractThe synthesis of cages with a polyradical framework remains a challenging task. Herein is reported an enantiomeric pair of quinoid-bridged polyradical tetrahedral palladium(II) cages that are stabilized by an unusual dianionic diradical form (dhbq..2−). These cages have been characterized by electron paramagnetic resonance and UV-visible spectroscopy, squid magnetometry and mass spectrometry. Single-crystal-derived X-ray investigations of the iso-structural cages built on fluoranilate linkers confirm the tetrahedral structure of the obtained radical cages. Theoretical calculations showed that the diradical state of the dhbq anions is more stable than the usual monoradical state. A weak ferromagnetic exchange between adjacent radical centers was observed in DFT studies.en_US
dc.identifier.citationChemistry—A European Journal, 27(39), 10012-10015.en_US
dc.identifier.issn0947-6539en_US
dc.identifier.issn1521-3765en_US
dc.identifier.sourcetitleChemistry—A European Journalen_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/5930
dc.identifier.urihttps://doi.org/10.1002/chem.202101239
dc.language.isoenen_US
dc.publication.originofpublisherForeignen_US
dc.publisherWileyen_US
dc.subjectCagesen_US
dc.subjectChiralityen_US
dc.subjectPalladiumen_US
dc.subjectP-N ligandsen_US
dc.subjectRadicalsen_US
dc.subject2021-JUN-WEEK2en_US
dc.subjectTOC-JUN-2021en_US
dc.subject2021en_US
dc.titleEnantiopure Polyradical Tetrahedral Pd12L6 Cagesen_US
dc.typeArticleen_US

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