Hypervalent Iodine Mediated Synthesis of C-2 Deoxy Glycosides and Amino Acid Glycoconjugates
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American Chemical Society
Abstract
A simple, efficient, and practical method for the synthesis of C-2 deoxy-2-iodo glycoconjugates in self-assembled structures was found using PhI(OCOR)2. 2-Iodo glycoserinyl esters were intramolecularly converted into 2-iodo serinyl glycosides which upon dehalogenation gave C-2 deoxy amino acid glycoconjugates.
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Journal of Organic Chemistry, 79(10), 4470-4476.