Selective Anion Exchange and Tunable Luminescent Behaviors of Metal–Organic Framework Based Supramolecular Isomers

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dc.contributor.authorManna, Biplaben_US
dc.contributor.authorSingh, Shwetaen_US
dc.contributor.authorKarmakar, Avisheken_US
dc.contributor.authorDESAI, AAMOD V.en_US
dc.contributor.authorGHOSH, SUJIT K.en_US
dc.contributor.departmentDept. of Chemistryen_US
dc.date.accessioned2019-03-15T11:23:39Z
dc.date.available2019-03-15T11:23:39Z
dc.date.issued2015-01en_US
dc.description.abstractOwing to the conformational (cis or trans) flexibility of a N-donor ligand, the combinations of the same and Cd(ClO4)2 under variable solvent templates afforded two supramolecular isomers based on two-dimensional metal–organic frameworks. Both compounds contain weakly coordinating ClO4– anions attached to the metal centers. Both frameworks showed facile anion exchange behaviors with various kinds of foreign anions. Moreover, both frameworks showed anion-driven structural dynamism and exhibited the preferential uptake of strongly coordinating anions over others. Anion-regulated modulation in luminescent behaviors was also observed in both cases.en_US
dc.identifier.citationInorganic Chemistry, 54 (1), 110-116.en_US
dc.identifier.issn0020-1669en_US
dc.identifier.issn1520-510Xen_US
dc.identifier.sourcetitleInorganic Chemistryen_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2192
dc.identifier.urihttps://doi.org/10.1021/ic501879w
dc.language.isoenen_US
dc.publication.originofpublisherForeignen_US
dc.publisherAmerican Chemical Societyen_US
dc.subjectAnion Exchangeen_US
dc.subjectLuminescent Behaviorsen_US
dc.subjectSupramolecular Isomersen_US
dc.subjectOrganic Frameworken_US
dc.subjectSEM imagesen_US
dc.subject2015en_US
dc.titleSelective Anion Exchange and Tunable Luminescent Behaviors of Metal–Organic Framework Based Supramolecular Isomersen_US
dc.typeArticleen_US

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