Synthesis and Crystal Structure of a Zn(II)-Based MOF Bearing Neutral N-Donor Linker and SiF62− Anion

Abstract

A novel three-dimensional two-fold interpenetrated bi-porous metal-organic framework IPM-325 (IPM: IISER Pune Materials) having pcu topology was synthesized at room temperature. Single crystal X-ray diffraction (SC-XRD) study revealed that the compound crystallizes in monoclinic lattice with molecular formula {[Zn(L)2 (SiF6)] (CH2Cl2) xG}n where G = Guests). All metal centers were found to have octahedral geometry. From single crystal analysis it can be inferred that SiF62− anion play a vital role in extending the dimensionality of the framework by bridging between two metal centers. Interestingly, IPM-325 exhibited two-step structural transformation maintaining the crystallinity of the framework as characterized by powder X-ray diffraction (PXRD).