Tin(ii) chloride assisted synthesis of N-protected γ-amino β-keto esters through semipinacol rearrangement

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dc.contributor.authorBANDYOPADHYAY, ANUPAMen_US
dc.contributor.authorAgrawal, Nehaen_US
dc.contributor.authorMALI, SACHITANAND M.en_US
dc.contributor.authorJADHAV, SANDIP V.en_US
dc.contributor.authorGOPI, HOSAHUDYA N.en_US
dc.contributor.departmentDept. of Chemistryen_US
dc.date.accessioned2019-01-21T10:29:25Z
dc.date.available2019-01-21T10:29:25Z
dc.date.issued2010-11en_US
dc.description.abstractA facile synthetic route for the preparation of N-protected γ-amino β-keto esters from amino aldehydes and ethyl diazoacetate is described. The two component coupling is facilitated by tin(II) chloride followed by semipinacol rearrangement leading to the product in quantitative yield. The reaction is mild, instantaneous and compatible with Boc-, Fmoc- and Cbz-amino protecting groups.en_US
dc.identifier.citationOrganic and Biomolecular Chemistry, (21).en_US
dc.identifier.issn1477-0520en_US
dc.identifier.issn1477-0539en_US
dc.identifier.sourcetitleOrganic and Biomolecular Chemistryen_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1493
dc.identifier.urihttps://doi.org/10.1039/C0OB00199F
dc.language.isoenen_US
dc.publication.originofpublisherForeignen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectchlorideen_US
dc.subjectamino aldehydesen_US
dc.subject2010en_US
dc.titleTin(ii) chloride assisted synthesis of N-protected γ-amino β-keto esters through semipinacol rearrangementen_US
dc.typeArticleen_US

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