Direct coordination of a germanium(II) dicationic center to transition metals

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dc.contributor.authorRauta, Ravindra K.en_US
dc.contributor.authorMAJUMDAR, MOUMITAen_US
dc.contributor.departmentDept. of Chemistryen_US
dc.date.accessioned2019-07-01T05:35:13Z
dc.date.available2019-07-01T05:35:13Z
dc.date.issued2017-01en_US
dc.description.abstractThe germanium(II) center of dicationic compound 1 donates an electron pair to transition metal Ag(I) and Au(I) cations, leading to complexes 2 and 3 respectively. Complex 3 is stabilized by [Ge:]2+→Au(I) σ-donation and π-back donation from filled d-orbitals of Au(I) to the two sets of p-orbitals available on Ge(II) centers.en_US
dc.identifier.citationChemical Communications, 53(9), 1467-1469 .en_US
dc.identifier.issn1359-7345en_US
dc.identifier.issn1364-548Xen_US
dc.identifier.sourcetitleChemical Communicationsen_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/3268
dc.identifier.urihttps://doi.org/10.1039/C6CC09525A
dc.language.isoenen_US
dc.publication.originofpublisherForeignen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectDirect coordinationen_US
dc.subjectDicationic centeren_US
dc.subjectTransition metalsen_US
dc.subjectAzamacrocyclesen_US
dc.subject2017en_US
dc.titleDirect coordination of a germanium(II) dicationic center to transition metalsen_US
dc.typeArticleen_US

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