Aerobic Dehydrogenative α-Diarylation of Benzyl Ketones with Aromatics through Carbon–Carbon Bond Cleavage

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dc.contributor.authorMore, Nagnath Yadaven_US
dc.contributor.authorJEGANMOHAN, MASILAMANIen_US
dc.contributor.departmentDept. of Chemistryen_US
dc.date.accessioned2019-02-25T09:02:09Z
dc.date.available2019-02-25T09:02:09Z
dc.date.issued2014-02en_US
dc.description.abstractSubstituted benzyl ketones reacted with aromatics in the presence of K2S2O8 in CF3COOH at room temperature, yielding α-diaryl benzyl ketones through a carbon–carbon bond cleavage. In the reaction, two new carbon–carbon bonds were formed and one carbon–carbon bond was cleaved. It is very interesting that two different nucleophiles such as benzyl ketones and aromatics were coupled together without metal, which is unusual in organic synthesis.en_US
dc.identifier.citationOrganic Letters, 16(3), 804-807.en_US
dc.identifier.issn1523-7060en_US
dc.identifier.issn1523-7052en_US
dc.identifier.sourcetitleOrganic Lettersen_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/1962
dc.identifier.urihttps://doi.org/10.1021/ol500079y
dc.language.isoenen_US
dc.publication.originofpublisherForeignen_US
dc.publisherAmerican Chemical Societyen_US
dc.subjectAerobic Dehydrogenativeen_US
dc.subjectAromaticsen_US
dc.subjectCarbon Bond Cleavageen_US
dc.subjectOrganic synthesisen_US
dc.subject2014en_US
dc.titleAerobic Dehydrogenative α-Diarylation of Benzyl Ketones with Aromatics through Carbon–Carbon Bond Cleavageen_US
dc.typeArticleen_US

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