1000-fold enhancement in proton conductivity of a MOF using post-synthetically anchored proton transporters

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dc.contributor.authorShalini, Sorouten_US
dc.contributor.authorDhavale, Vishal M.en_US
dc.contributor.authorEldho, Kavalakal M.en_US
dc.contributor.authorKurungot, Sreekumaren_US
dc.contributor.authorAjithkumar, Thallaseril G.en_US
dc.contributor.authorVAIDHYANATHAN, RAMANATHANen_US
dc.contributor.departmentDept. of Chemistryen_US
dc.date.accessioned2019-04-29T10:17:20Z
dc.date.available2019-04-29T10:17:20Z
dc.date.issued2016-08en_US
dc.description.abstractPyridinol, a coordinating zwitter-ionic species serves as stoichiometrically loadable and non-leachable proton carrier. The partial replacement of the pyridinol by stronger hydrogen bonding, coordinating guest, ethylene glycol (EG), offers 1000-fold enhancement in conductivity (10−6 to 10−3 Scm−1) with record low activation energy (0.11 eV). Atomic modeling coupled with 13C-SSNMR provides insights into the potential proton conduction pathway functionalized with post-synthetically anchored dynamic proton transporting EG moieties.en_US
dc.identifier.citationScientific Reports, 6, 32489.en_US
dc.identifier.issn2045-2322en_US
dc.identifier.sourcetitleScientific Reportsen_US
dc.identifier.urihttp://dr.iiserpune.ac.in:8080/xmlui/handle/123456789/2747
dc.identifier.urihttps://doi.org/10.1038/srep32489
dc.language.isoenen_US
dc.publication.originofpublisherForeignen_US
dc.publisherNature Publishing Groupen_US
dc.subject1000-fold enhancementen_US
dc.subjectProton conductivityen_US
dc.subjectAnchored proton transportersen_US
dc.subjectDynamic proton transportingen_US
dc.subject2016en_US
dc.title1000-fold enhancement in proton conductivity of a MOF using post-synthetically anchored proton transportersen_US
dc.typeArticleen_US

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